Por que a superfície do gelo é molhada?

segunda-feira, dezembro 05, 2016

Thermodynamic origin of surface melting on ice crystals

Ken-ichiro Murata a,1, Harutoshi Asakawa b, Ken Nagashima a, Yoshinori Furukawa a, and Gen Sazaki a

Author Affiliations

aInstitute of Low Temperature Science, Hokkaido University, Kita-ku, Sapporo 060-0819, Japan;

bGraduate School of Sciences and Technology for Innovation, Yamaguchi University, Yoshida, Yamaguchi 753-8512, Japan

Edited by Pablo G. Debenedetti, Princeton University, Princeton, NJ, and approved September 8, 2016 (received for review June 2, 2016)


Significance

Phase transitions of ice are a major source of a diverse set of natural phenomena on Earth. In particular, quasi-liquid layers (QLLs) resulting from surface melting are recognized to be key players involved in various natural phenomena spanning from making snowballs to electrification of thunderclouds. With the aid of in situ observations with our advanced optical microscopy combined with two-beam interferometry, we elucidate a thermodynamic origin of the formation of QLLs and their unique wetting behavior (pseudo-partial wetting and wetting transitions) on ice surfaces. We show that QLLs are a metastable transient state formed through vapor growth and sublimation of ice that are absent at equilibrium.

Abstract

Since the pioneering prediction of surface melting by Michael Faraday, it has been widely accepted that thin water layers, called quasi-liquid layers (QLLs), homogeneously and completely wet ice surfaces. Contrary to this conventional wisdom, here we both theoretically and experimentally demonstrate that QLLs have more than two wetting states and that there is a first-order wetting transition between them. Furthermore, we find that QLLs are born not only under supersaturated conditions, as recently reported, but also at undersaturation, but QLLs are absent at equilibrium. This means that QLLs are a metastable transient state formed through vapor growth and sublimation of ice, casting a serious doubt on the conventional understanding presupposing the spontaneous formation of QLLs in ice–vapor equilibrium. We propose a simple but general physical model that consistently explains these aspects of surface melting and QLLs. Our model shows that a unique interfacial potential solely controls both the wetting and thermodynamic behavior of QLLs.

surface melting quasi-liquid layer advanced optical microscopy pseudo-partial wetting wetting transition

Footnotes

1To whom correspondence should be addressed. Email: murata@lowtem.hokudai.ac.jp.

Author contributions: K.-i.M. and G.S. designed research; K.-i.M., H.A., K.N., Y.F., and G.S. performed research; K.-i.M. analyzed data; and K.-i.M. wrote the paper.

The authors declare no conflict of interest.

This article is a PNAS Direct Submission.

See Commentary on page 12347.

This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1608888113/-/DCSupplemental.

Freely available online through the PNAS open access option.

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